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CMS-SMP-24-014 ; CERN-EP-2026-102
Evidence of $ \mathrm{Z}\mathrm{Z}\gamma $ production and observation of 4 $ \ell\gamma $ in proton-proton collisions at $ \sqrt{s} = $ 13 TeV
Submitted to Physical Review Letters
Abstract: Evidence of the production of two Z bosons and a photon in proton-proton collisions is reported for the first time in CMS. The analysis uses data collected by the CMS experiment between 2016 and 2018 at a center-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 138 fb$ ^{-1} $. The first evidence for the process $ \mathrm{p}\mathrm{p}\to\mathrm{Z}\mathrm{Z}\gamma\to4\ell\gamma $ ($ \ell = \mathrm{e} $, $ \mu $), with an observed (expected) significance of 3.7 (3.1) standard deviations in a fiducial region defined by $ p_{\mathrm{T}}^\gamma > $ 20 GeV, $ |\eta^\gamma| < $ 2.4, $ \Delta R(\ell,\gamma) > $ 0.5, $ m_{\mathrm{Z}} $ between 60 and 120 GeV, and the invariant mass of either of the two Z bosons combined with the photon ($ m_{\mathrm{Z}\gamma} $) larger than 100 GeV, is reported. The measured (predicted) fiducial cross section is 60 $ ^{+27}_{-22} $ ab ( 47.56 $ \pm $ 0.04 ab). Additionally, the inclusive production of $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ is studied by removing the $ m_{\mathrm{Z}\gamma} $ requirement to include final state radiation where one Z boson decays to 2 $ \ell\gamma $, yielding an observed (expected) significance of 5.0 (4.2) standard deviations and a measured (predicted) fiducial cross section of 156 $ ^{+39}_{-35} $ ab ( 99.97 $ \pm $ 0.09 ab).
Figures & Tables Summary References CMS Publications
Figures

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Figure 1:
Representative tree-level standard model Feynman diagrams with four isolated leptons and a photon in the final state. From left to right, photon emitted from a quark line, associated ZH production, and final-state radiation.

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Figure 1-a:
Representative tree-level standard model Feynman diagrams with four isolated leptons and a photon in the final state. From left to right, photon emitted from a quark line, associated ZH production, and final-state radiation.

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Figure 1-b:
Representative tree-level standard model Feynman diagrams with four isolated leptons and a photon in the final state. From left to right, photon emitted from a quark line, associated ZH production, and final-state radiation.

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Figure 1-c:
Representative tree-level standard model Feynman diagrams with four isolated leptons and a photon in the final state. From left to right, photon emitted from a quark line, associated ZH production, and final-state radiation.

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Figure 2:
Transverse momentum (left) and pseudorapidity (right) of the leading photon passing the loose selection and failing the tight cutoff-based identification in the nonprompt photon application region with four tight leptons. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.

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Figure 2-a:
Transverse momentum (left) and pseudorapidity (right) of the leading photon passing the loose selection and failing the tight cutoff-based identification in the nonprompt photon application region with four tight leptons. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.

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Figure 2-b:
Transverse momentum (left) and pseudorapidity (right) of the leading photon passing the loose selection and failing the tight cutoff-based identification in the nonprompt photon application region with four tight leptons. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.

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Figure 3:
Post-fit mass distributions of the $ \mathrm{Z}\mathrm{Z}\gamma $ system in the triboson $ \mathrm{Z}\mathrm{Z}\gamma $ (left) and inclusive $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ (right) regions, obtained with the cutoff-based and multivariate photon identification, respectively. The last bin includes the events exceeding the upper bound of the x-axis. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.

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Figure 3-a:
Post-fit mass distributions of the $ \mathrm{Z}\mathrm{Z}\gamma $ system in the triboson $ \mathrm{Z}\mathrm{Z}\gamma $ (left) and inclusive $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ (right) regions, obtained with the cutoff-based and multivariate photon identification, respectively. The last bin includes the events exceeding the upper bound of the x-axis. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.

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Figure 3-b:
Post-fit mass distributions of the $ \mathrm{Z}\mathrm{Z}\gamma $ system in the triboson $ \mathrm{Z}\mathrm{Z}\gamma $ (left) and inclusive $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ (right) regions, obtained with the cutoff-based and multivariate photon identification, respectively. The last bin includes the events exceeding the upper bound of the x-axis. The vertical bars represent the statistical uncertainties in the data. The hatched area represents the statistical uncertainties in the simulation.
Tables

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Table 1:
Post-fit event yields in the triboson $ \mathrm{Z}\mathrm{Z}\gamma $ (left) and inclusive 4 $ \ell\gamma $ (right) regions. Uncertainties are statistical only. The row labeled $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ OOA (out-of-acceptance) gives the number of events in the $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ signal sample failing the fiducial selection.
Summary
In summary, this Letter presents the first evidence in CMS for triboson production, $ \mathrm{p}\mathrm{p}\to\mathrm{Z}\mathrm{Z}\gamma\to4\ell\gamma $, where both Z bosons decay leptonically to electrons or muons, in proton-proton collisions at $\sqrt{s}=13$ TeV, collected in 2016--2018 and corresponding to an integrated luminosity of 138 fb$ ^{-1} $. The fiducial cross section, $\sigma_{\text{fid}} = 60^{+27}_{-22}$ ab, is the smallest ever measured at the LHC. In a more inclusive signal region with FSR contributions, $ \mathrm{p}\mathrm{p}\to4\ell\gamma $ production is also observed, with a fiducial cross section of $156^{+39}_{-35}$ ab. The results are in good agreement with standard model predictions.
References
1 ATLAS Collaboration Measurement of $ \mathrm{Z}\gamma\gamma $ production in pp collisions at $ \sqrt{s} = $ 13 TeV with the ATLAS detector Eur. Phys. J. C. 83 (2023) 539 2211.14171
2 ATLAS Collaboration Observation of $ \mathrm{W}\gamma\gamma $ triboson production in proton-proton collisions at $ \sqrt{s}= $ 13 TeV with the ATLAS detector Phys. Lett. B. 848 (2024) 138400 2308.03041
3 CMS Collaboration Measurements of the $ {\mathrm{p}}{\mathrm{p}}\to\mathrm{W^{\pm}}\gamma\gamma $ and $ {\mathrm{p}}{\mathrm{p}}\to\mathrm{Z}\gamma\gamma $ cross sections at $ \sqrt s = $ 13 TeV and limits on anomalous quartic gauge couplings JHEP 10 (2021) 174 CMS-SMP-19-013
2105.12780
4 ATLAS Collaboration Observation of $ \mathrm{W}\mathrm{Z}\gamma $ production in pp collisions at $ \sqrt{s}= $ 13 TeV with the ATLAS Detector PRL 132 (2024) 021802 2305.16994
5 CMS Collaboration Observation of $ \mathrm{W}\mathrm{Z}\gamma $ production and constraints on new physics scenarios in proton-proton collisions at $ \sqrt{s} = $ 13 TeV PRD 112 (2025) 012009 CMS-SMP-22-018
2503.21977
6 ATLAS Collaboration Observation of $ \mathrm{W^+}\mathrm{W^-}\gamma $ production in pp collisions at $ \sqrt{s} = $ 13 TeV with the ATLAS detector and constraints on anomalous quartic gauge-boson couplings PLB 873 (2026) 140050 2509.14070
7 CMS Collaboration Observation of WW$ \gamma $ production and search for H$ \gamma $ production in proton-proton collisions at $ \sqrt{s} = $ 13 TeV PRL 132 (2024) 121901 CMS-SMP-22-006
2310.05164
8 ATLAS Collaboration Evidence for the production of three massive vector bosons with the ATLAS detector PLB 798 (2019) 134913 1903.10415
9 CMS Collaboration Observation of the production of three massive gauge bosons at $ \sqrt{s} = $ 13 TeV PRL 125 (2020) 151802 CMS-SMP-19-014
2006.11191
10 ATLAS Collaboration Evidence of $ ZZ\gamma $ production with the ATLAS detector Submitted to Phys. Rev. Lett, 2026 2602.17165
11 ATLAS Collaboration Exploration at the high-energy frontier: ATLAS Run 2 searches investigating the exotic jungle beyond the Standard Model Phys. Rep. 1116 301, 2024 2403.09292
12 CMS Collaboration Stairway to discovery: a report on the CMS programme of cross section measurements from millibarns to femtobarns Phys. Rep. 1115 (2025) 3 CMS-SMP-23-004
2405.18661
13 CMS Collaboration HEPData record for this analysis link
14 CMS Collaboration The CMS experiment at the CERN LHC JINST 3 (2008) S08004
15 CMS Collaboration Development of the CMS detector for the CERN LHC Run 3 JINST 19 (2024) P05064 CMS-PRF-21-001
2309.05466
16 CMS Collaboration Performance of the CMS Level-1 trigger in proton-proton collisions at $ \sqrt{s} = $ 13 TeV JINST 15 (2020) P10017 CMS-TRG-17-001
2006.10165
17 CMS Collaboration The CMS trigger system JINST 12 (2017) P01020 CMS-TRG-12-001
1609.02366
18 CMS Collaboration Performance of the CMS high-level trigger during LHC Run 2 JINST 19 (2024) P11021 CMS-TRG-19-001
2410.17038
19 CMS Collaboration Electron and photon reconstruction and identification with the CMS experiment at the CERN LHC JINST 16 (2021) P05014 CMS-EGM-17-001
2012.06888
20 CMS Collaboration Performance of the CMS muon detector and muon reconstruction with proton-proton collisions at $ \sqrt{s} = $ 13 TeV JINST 13 (2018) P06015 CMS-MUO-16-001
1804.04528
21 CMS Collaboration Description and performance of track and primary-vertex reconstruction with the CMS tracker JINST 9 (2014) P10009 CMS-TRK-11-001
1405.6569
22 CMS Collaboration Particle-flow reconstruction and global event description with the CMS detector JINST 12 (2017) P10003 CMS-PRF-14-001
1706.04965
23 CMS Collaboration Performance of reconstruction and identification of $ \tau $ leptons decaying to hadrons and $ \nu_{\tau} $ in pp collisions at $ \sqrt{s} = $ 13 TeV JINST 13 (2018) P10005 CMS-TAU-16-003
1809.02816
24 CMS Collaboration Jet energy scale and resolution in the CMS experiment in pp collisions at 8 TeV JINST 12 (2017) P02014 CMS-JME-13-004
1607.03663
25 CMS Collaboration Performance of missing transverse momentum reconstruction in proton-proton collisions at $ \sqrt{s} = $ 13 TeV using the CMS detector JINST 14 (2019) P07004 CMS-JME-17-001
1903.06078
26 J. Alwall et al. The automated computation of tree-level and next-to-leading order differential cross sections, and their matching to parton shower simulations JHEP 07 (2014) 079 1405.0301
27 R. Frederix et al. The automation of next-to-leading order electroweak calculations JHEP 07 (2018) 1804.10017
28 P. Nason A new method for combining NLO QCD with shower Monte Carlo algorithms JHEP 11 (2004) 040 hep-ph/0409146
29 S. Frixione, P. Nason, and C. Oleari Matching NLO QCD computations with parton shower simulations: the POWHEG method JHEP 11 (2007) 070 0709.2092
30 S. Alioli, P. Nason, C. Oleari, and E. Re A general framework for implementing NLO calculations in shower Monte Carlo programs: the POWHEG BOX JHEP 06 (2010) 043 1002.2581
31 T. Melia, P. Nason, R. Rontsch, and G. Zanderighi $ \mathrm{W}^+\mathrm{W}^- $, WZ and $ ZZ $ production in the POWHEG BOX JHEP 11 (2011) 078 1107.5051
32 P. Nason and G. Zanderighi $ \mathrm{W^+}\mathrm{W^-} $, WZ and ZZ production in the POWHEG-BOX-V2 EPJC 74 (2014) no. 1, 2702 1311.1365
33 J. M. Campbell and R. K. Ellis MCFM for the Tevatron and the LHC Nucl. Phys. Proc. Suppl. 205 (2010) 10 1007.3492
34 T. Sjöstrand et al. An introduction to PYTHIA 8.2 Comput. Phys. Commun. 191 (2015) 159 1410.3012
35 CMS Collaboration Extraction and validation of a new set of CMS PYTHIA-8 tunes from underlying-event measurements Eur. Phys. J. C. 80 (2020) 4 CMS-GEN-17-001
1903.12179
36 GEANT4 Collaboration GEANT4---a simulation toolkit NIM A 506 (2003) 250
37 NNPDF Collaboration Parton distributions for the LHC run II JHEP 04 (2015) 040 1410.8849
38 CMS Collaboration Technical proposal for the phase-II upgrade of the Compact Muon Solenoid CMS Technical proposal CERN-LHCC-2015-010, CMS-TDR-15-02, CERN, 2015
CDS
39 CMS Collaboration Measurements of inclusive and differential cross sections for the Higgs boson production and decay to four-leptons in proton-proton collisions at $ \sqrt{s} = $ 13 TeV JHEP 08 (2023) 040 CMS-HIG-21-009
2305.07532
40 CMS Collaboration Performance of the reconstruction and identification of high-momentum muons in proton-proton collisions at $ \sqrt{s} = $ 13 TeV JINST 15 (2020) P02027 CMS-MUO-17-001
1912.03516
41 CMS Collaboration Measurement of the ZZ production cross section and $ \mathrm{ Z } \to {\ell^+\ell^-\ell^{\prime+}\ell^{\prime-}} $ branching fraction in pp collisions at $ \sqrt{s} = $ 13 TeV PLB 763 (2016) 280 CMS-SMP-16-001
1607.08834
42 CMS Collaboration Measurement of vector boson scattering and constraints on anomalous quartic couplings from events with four leptons and two jets in proton-proton collisions at $ \sqrt{s} = $ 13 TeV PLB 774 (2017) 682 CMS-SMP-17-006
1708.02812
43 CMS Collaboration Evidence for electroweak production of four charged leptons and two jets in proton-proton collisions at $ \sqrt{s} = $ 13 TeV PLB 812 (2020) 135992 CMS-SMP-20-001
2008.07013
44 CMS Collaboration Measurement of differential ZZ + jets production cross sections in pp collisions at $ \sqrt{s} = $ 13 TeV JHEP 10 (2024) 209 CMS-SMP-22-001
2404.02711
45 CMS Collaboration Measurement of the properties of a Higgs boson in the four-lepton final state PRD 89 (2014) 092007 CMS-HIG-13-002
1312.5353
46 J. Butterworth et al. PDF4LHC recommendations for LHC Run II JPG 43 (2016) 023001 1510.03865
47 CMS Collaboration Precision luminosity measurement in proton-proton collisions at $ \sqrt{s} = $ 13 TeV in 2015 and 2016 at CMS Eur. Phys. J. C. 81 (2021) 800 CMS-LUM-17-003
2104.01927
48 CMS Collaboration CMS luminosity measurement for the 2017 data-taking period at $ \sqrt{s}= $ 13 TeV CMS Physics Analysis Summary, 2018
CMS-PAS-LUM-17-004
CMS-PAS-LUM-17-004
49 CMS Collaboration CMS luminosity measurement for the 2018 data-taking period at $ \sqrt{s}= $ 13 TeV CMS Physics Analysis Summary, 2019
CMS-PAS-LUM-18-002
CMS-PAS-LUM-18-002
50 CMS Collaboration Measurement of the inelastic proton-proton cross section at $ \sqrt{s} = $ 13 TeV JHEP 07 (2018) 161 CMS-FSQ-15-005
1802.02613
51 CMS Collaboration The CMS statistical analysis and combination tool: COMBINE Comput. Softw. Big. Sci. 8 (2024) 19 CMS-CAT-23-001
2404.06614
Compact Muon Solenoid
LHC, CERN